LiPo chemistry: cells operate between 3.0V (depleted) and 4.2V (fully charged) per cell, with 3.7V nominal. Cell imbalance develops over time as individual cells age at different rates — one cell hits 3.0V cutoff before others, and the BMS stops discharge to protect it, leaving capacity in the other cells unused. Balance charging (which DJI's standard charger does automatically) helps slow this but cannot prevent it indefinitely over many cycles.
Temperature effects: at 0 degrees C, available capacity drops approximately 20-30%; at -10 degrees C, up to 40-50% capacity loss. Cold slows the electrochemical reaction rate and increases internal cell resistance, causing sharper voltage sag under motor load. This voltage sag is what triggers premature low battery warnings in cold weather — the BMS measures voltage and interprets the sag as low charge even though the cells are not actually depleted.